Product ID:LIQUID STAPLES
MSDS Date:05/23/1990
FSC:8040
NIIN:00N037725
MSDS Number: CDWFN

UNCOMMON CONGLOMERATES INC

287 EAST 6TH ST
ST PAUL, MN 55101
US

Emergency Phone: 800-228-5635

Info Phone: 800-323-4545

Cage: 0AW86

UNCOMMON CONGLOMERATES INC

ST PAUL, MN 55103-2257 US

Telephone: 651-227-7000/800-323-4545

Cage: 0AW86

ALONE. NEVER GIVE ANYTHING TO DRINK TO PERS WHO IS

RTECS: 9999999ZZ

CLTHG, CLEAR AIRWAY, & KEEP PERS WARM. NOTE TO

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THIS EFT IS POTENTIATED BY ENDOGENOUS ADRENERGIC

RTECS: 9999999ZZ

EXCITEMENT/BY ADMIN OF EPINEPHRINE-LIKE DRUGS. SUCH

RTECS: 9999999ZZ

MONITORING IS AVAILABLE.

RTECS: 9999999ZZ

APPROP SYNTHETIC ABSORBENT. PLACE CONTAMD MATL

RTECS: 9999999ZZ

DO NOT FLUSH TO SEWER, STREAM/OTHER BODIES OF WATER

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TO CONTACT APPROPRIATE GOVERNMENT

RTECS: 9999999ZZ

IT CAN RETAIN PRODUCT RESIDUES. THEREFORE,

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FOR HUMAN OR ANIMAL CONSUMPTION OR WHERE SKIN

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AND FULL LENGTH FACESHIELD .

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SHOULD BE THOROUGHLY CLEANED AND DRIED BEFORE

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METHANE, DICHLORO-; (METHYLENE CHLORIDE/DICHLOROMETHANE)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 80-90%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

DIZZ, HDCHS, & INCOORD. CAN CAUSE ANESTH

RTECS: 9999999ZZ

& ESOPHAGUS. DIZZ, FAINTNESS, DROW, & INCOORD

RTECS: 9999999ZZ

FREQUENCY, & DURATION OF EXPOS, TOX MAY OCCUR IN THE

RTECS: 9999999ZZ

PERIPHERAL NERVOUS SYSTEM, BLOOD AND/OR HEMATOPOIETIC

RTECS: 9999999ZZ

CALL A POIS CTL CTR, EMER ROOM/MD.

RTECS: 9999999ZZ

SYRUP OF IPECAC FOLLOWED BY 2 GLASSES OF H*2O/BY

RTECS: 9999999ZZ

HIGH RISK OF ASPIR & SUBSEQUENT CHEM PNEUM. IF PERS

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL, RAT): 2136 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFT IN HUMANS. ADRENOMIMETICS (IE,
EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAINING
USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . EYE
CNTCT:LIQ (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS
SUPPLEMENT, VOL 7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON
CARCIN, (SUPDAT)
Effects of Overexposure:HLTH HAZ:CAN CAUSE MILD TO MOD IRRIT. VAPS
&/MIST CAN CAUSE MILD TO MOD IRRIT. SKIN CNTCT:CAN CAUSE MILD TO
MOD IRRIT. PRLNG CNTCT CAN DEFAT THE SKIN, CAUSE IRRIT, & LEAD TO
DEVELOPMENT OF DERM. HARMF UL WHEN ABSORBED IN SUFFICIENT AMTS.
INHAL:CAN CAUSE IRRIT TO THE NOSE, THROAT, & UPPER RESP TRACT. CAN
CAUSE (ING 2)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/MED CNDTNS INVOLVING
FOLLOWING ORGAN(S) &/SYS(S) SHOULD TAKE APPROP PREC WHEN HNDLG THIS
PROD: LIVER, KIDNEY, NERVOUS SYS (CENTRAL &/PERIPHERAL), BLOOD
&/HEMATOPOIETIC, HEART/CVS, SKIN.

First Aid:EYE:FLUSH W/STEADY STEAM OF H*2O FOR AT LEAST 15 MIN. LIFT
UPPER & LOWER EYE LIDS FREQUENTLY. GET PROMPT MED ATTN. SKIN:REMOVE
CONTAMD CLTHG & SHOES. WASH AFFECTED AREA W/MILD SOAP & PLENTY OF
H*2O. I F IRRIT DEVELOPS, CONSULT A MD. WASH CONTAMD CLTHG BEFORE
REUSE. INHAL:REMOVE TO FRESH AIR. IF SYMPS DEVELOP, SEEK IMMED MED
ATTN. IF NOT BRTHG, GIVE ARTF RESP, PREFERABLY MOUTH TO MOUTH. (ING
6)

Flash Point Method:SCC
Flash Point:>200F,>93C
Extinguishing Media:SMALL FIRES:USE AGENTS APPRVD FOR CLASS B HAZS
(E.G. DRY CHEM, CARBON DIOXIDE, HALON, FOAM, STEAM)/WATER FOG.
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMP PROD MAY INCL HCL &
PHOSGENE . WHEN EXPOS TO FLAMES/HIGH TEMP NORMALY ENCOUNTERED
DURING FIRE CNDTNS, SEALED (SUPDAT)

Spill Release Procedures:STOP DISCHARGE & CNTN SPILL USING A
DIKE/BARRIER. IF A SUBSTANTIAL QTY IS SPILLED, & CAN BE PUMPED,
RECOVER W/PUMPING EQUIP/VACUUM TRUCK. EXPLOSION-PROOF EQUIP SHOULD
BE USED, OTHERWISE, USE AN ABSORB SUCH AS FULLER'S EARTH,
CLAY/OTHER (ING 14)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENT AREA. NO
SPECIAL PRECS ARE NEEDED. FOLLOW GOOD MFG & HNDLG PRACTICES. THIS
CNTNR CAN BE HAZ WHEN EMPTY, BECAUSE(ING 17)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR
PHOSGENE .

Respiratory Protection:WEAR NIOSH APPRVD EQUIP. DETERM APPROP TYPE
EQUIP FOR SPECIFIC APPLICATN BY CONSULTING RESP MFR. HIGH AIRBORNE
CONC MAY NECESSITATE THE USE OF SCBA/SUPPLIED AIR RESP. IN ADDITON,
RESP PROT PROGRAMS MU ST BE IN COMPLIANCE W/29 CFR 1910.134
Ventilation:GENERAL (DILUTION) VENT MAY BE ACCEPTABLE. HOWEVER, LOCAL
EXHAUST VENT IS RECD WHEN VAP, MISTS/DUST CAN BE RELEASED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 19)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THORO AFTER HNDLG, ESP BEFORE EATING,
DRINKING, SMOKING/USING RESTROOM FACILITIES. CONTAMD CLTHG & SHOES
(ING 20)
Supplemental Safety and Health
EXTING MEDIA:LARGE FIRES:USE WATER SPRAY, FOG/ALCOHOL FOAM. EXPLO
HAZ:CNTNRS MAY RUPTURE DUE TO A BUILDUP OF INTERNAL PRESS. COOL
CNTNRS W/H*2O. MAY LIBERATE IRRIT VAPS DURING COMBUST/DECOMP. HAZ
DECO MP PROD:CARBON MONOXIDE). EXPLAN OF CARCIN:1994:ANTIC TO BE
CARCIN. ANIMAL: LUNG, LIV, SALIVARY, MAMMARY GLAND (TUMORS).

Spec Gravity:1.32 (H*2O = 1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID, SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS. ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PHOSGENE . HYDROGEN CHLORIDE. SMOKE,
SOOT, & TOXIC FUMES (E.G. CARBON DIOXIDE & (SUPDAT)

Waste Disposal Methods:IF DISCARDED IN ITS ORGINAL UNUSED FORM, THIS
PROD DOES NOT MEET THE DEFINITION OF A RCRA HAZ WASTE UNDER 40 CFR
261. NEVERTHELESS, IT SHOULD BE MANAGED AT AN AUTHORIZED FACILITY,
IN COMPLIANCE W/ALL APPLIC FED, STATE, & LOCAL REQS. BE SURE (ING
16)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.